ON α-LIKE RADICALS
نویسندگان
چکیده
منابع مشابه
Do α-acyloxy and α-alkoxycarbonyloxy radicals fragment to form acyl and alkoxycarbonyl radicals?
The generation of alpha-acyloxy and alpha-alkoxycarbonyloxy radicals under reductive conditions in fragmentable probe experiments does not provide unequivocal evidence for the fragmentation of such radicals to give ketones and acyl or alkoxycarbonyl radicals. Instead, standard reduction predominates, even at low tin hydride concentrations. Some ketone product is formed in the alpha-acyloxy subs...
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ژورنال
عنوان ژورنال: Bulletin of the Australian Mathematical Society
سال: 2011
ISSN: 0004-9727,1755-1633
DOI: 10.1017/s0004972711002231